poonernigger 'toss but whatever
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Threads by latest replies - Page 182
OPSEC LEVEL: showing your fingernails so you will get deported by ICE
Canada could unirongenuinhonestly defeat iran in mere days if it truly wanted to
Congratulations to groyper candidate James "Bottom" Talarico
(you) could have had a cute klanswoman girlfriend but (((they))) took it away from you
Do you think in a few years people are gonna be talking about how those TF2 MGE edits made them gay for big muscular men?
Has this ever been debunked
Hello Dark True Crime Community ( /r/DarkTCC)
One thing worth knowing before you spend money: heating CBD does not make THC. Decarboxylation only converts CBDA>CBD. You need acid, not heat alone. That trips up a lot of people.
—
## The reaction: acid-catalyzed cyclization
CBD is a di-p-menthene. Acid protonates it, the ring closes, and you get THC isomers - mostly D8 with some D9, plus D8-iso-THC, CBN, and unreacted CBD. This is exactly how commercial D8 is made; there's no secret. The [Barrie patent](https://patents.google.com/patent/US7399872B2/en) is the canonical reference (300 mg CBD + 30 mg p-TsOH in 15 mL toluene, reflux 1 h, claims >=60% yield).
Shopping list: CBD isolate, n-heptane or VM&P naphtha, p-toluenesulfonic acid monohydrate, sodium bicarbonate, Epsom salt, 190-proof Everclear, borosilicate flask, magnetic stirrer hotplate, reflux condenser, thermometer, glass syringe + 0.45 um PTFE filters, separatory funnel or mason jars.
### Procedure, 10 g scale
1. 10 g CBD isolate into 150 mL heptane in a flask. Stir to dissolve.
2. Dissolve 1 g p-TsOH in 10 mL heptane, add it in.
3. Reflux at 85-100 degC for 2-3 h with stirring. Color goes gold > amber > orange. Longer and hotter pushes more D8 and more degradation; shorter and milder keeps more D9.
4. Cool. Add 100 mL water, swirl, separate.
5. Wash organic layer with water, then 5% sodium bicarbonate (kills the acid), then brine.
6. Dry over Epsom salt, filter, evaporate the heptane gently in a hot water bath with ventilation.
You're left with roughly 8-9 g of dark amber oil at 60-75% total THC, 8-15% unreacted CBD, and a pile of iso-THC junk. Clean it up by dissolving in ethanol, freezing 12 h, filtering cold, and evaporating again - that drops the waxes and some color.
Reality check: without vacuum distillation you will not get 90%+ and it will not be pretty. Commercial D8 is distilled; home crude is a tarry mess that tastes like burnt sugar. Short-path glassware plus a two-stage rotary vane pump (water aspirator won't pull hard enough) runs $250-400 and is a genuine skill curve.
Safety: 190-proof is flammable - hot plate, no gas flame, don't seal the flask. p-TsOH burns, gloves and goggles. Heptane is flammable and mildly neurotoxic; do this outside or under a hood.
—
## Spraying it on flower
Use ethanol for this step specifically - heptane residue is worse to smoke.
- Dissolve the oil in 190-proof at 1:4 to 1:5 (oil:solvent), warm slightly.
- Fine-mist atomizer or a cheap airbrush. Flower in a wide shallow tub or a big ziplock.
- Weigh the flower. Target 10-15% added oil by weight. Mist thin passes, tumble between each, 3-5 passes total, 5 minutes apart.
- Cure sealed 24-48 h, tumbling occasionally, then air out 12-24 h until the ethanol smell is gone.
What you're signing up for: greasy sticky bud that canoes, needs relighting, burns hot, and buries the Gorilla Glue terps under the oil. Also, once sprayed, the jar fails any total-THC test by a mile - but nobody is testing your personal stash.
—
## The box mod question
Crude oil will not work in a sub-ohm tank. Too viscous to wick, and dirty enough to foul the coil in a day.
Three real paths:
- Thin it. 10-20% CBC (a cannabinoid that's naturally thin and cheap) plus <=5% terpenes, in a ceramic-coil pod - Nord with an RPM ceramic 1.2O, or similar. Terpenes alone at high percentages are harsh and eat plastic tanks, which is why CBC matters.
- Dab it. A Sequoia/Divine Tribe-style dab tank or a wax pen handles raw oil fine. Just chazzes.
- Distill it. Only route to something that behaves like a real cart.
—
## My actual recommendation
Two things, and neither is the conversion.
Stockpile now. Buy 100 g of D8 distillate this week, split into amber syringes, freeze. That's maybe $150-250 and it's shelf-stable for years cold, dark, and oxygen-free. That single move covers the next several years of vaping and dosing, and it beats anything you'll produce in a kitchen.
Then learn the conversion as a hedge against distillate becoming hard to order, and point it at edibles and MCT tincture - not carts and not flower. Crude oil is genuinely excellent in a dropper bottle where color and harshness don't matter, and that's the one use case where the messy chemistry is a non-issue. Sprayed flower is a fun project, but it's the worst effort-to-payoff ratio of the three.
—
## The reaction: acid-catalyzed cyclization
CBD is a di-p-menthene. Acid protonates it, the ring closes, and you get THC isomers - mostly D8 with some D9, plus D8-iso-THC, CBN, and unreacted CBD. This is exactly how commercial D8 is made; there's no secret. The [Barrie patent](https://patents.google.com/patent/US7399872B2/en) is the canonical reference (300 mg CBD + 30 mg p-TsOH in 15 mL toluene, reflux 1 h, claims >=60% yield).
Shopping list: CBD isolate, n-heptane or VM&P naphtha, p-toluenesulfonic acid monohydrate, sodium bicarbonate, Epsom salt, 190-proof Everclear, borosilicate flask, magnetic stirrer hotplate, reflux condenser, thermometer, glass syringe + 0.45 um PTFE filters, separatory funnel or mason jars.
### Procedure, 10 g scale
1. 10 g CBD isolate into 150 mL heptane in a flask. Stir to dissolve.
2. Dissolve 1 g p-TsOH in 10 mL heptane, add it in.
3. Reflux at 85-100 degC for 2-3 h with stirring. Color goes gold > amber > orange. Longer and hotter pushes more D8 and more degradation; shorter and milder keeps more D9.
4. Cool. Add 100 mL water, swirl, separate.
5. Wash organic layer with water, then 5% sodium bicarbonate (kills the acid), then brine.
6. Dry over Epsom salt, filter, evaporate the heptane gently in a hot water bath with ventilation.
You're left with roughly 8-9 g of dark amber oil at 60-75% total THC, 8-15% unreacted CBD, and a pile of iso-THC junk. Clean it up by dissolving in ethanol, freezing 12 h, filtering cold, and evaporating again - that drops the waxes and some color.
Reality check: without vacuum distillation you will not get 90%+ and it will not be pretty. Commercial D8 is distilled; home crude is a tarry mess that tastes like burnt sugar. Short-path glassware plus a two-stage rotary vane pump (water aspirator won't pull hard enough) runs $250-400 and is a genuine skill curve.
Safety: 190-proof is flammable - hot plate, no gas flame, don't seal the flask. p-TsOH burns, gloves and goggles. Heptane is flammable and mildly neurotoxic; do this outside or under a hood.
—
## Spraying it on flower
Use ethanol for this step specifically - heptane residue is worse to smoke.
- Dissolve the oil in 190-proof at 1:4 to 1:5 (oil:solvent), warm slightly.
- Fine-mist atomizer or a cheap airbrush. Flower in a wide shallow tub or a big ziplock.
- Weigh the flower. Target 10-15% added oil by weight. Mist thin passes, tumble between each, 3-5 passes total, 5 minutes apart.
- Cure sealed 24-48 h, tumbling occasionally, then air out 12-24 h until the ethanol smell is gone.
What you're signing up for: greasy sticky bud that canoes, needs relighting, burns hot, and buries the Gorilla Glue terps under the oil. Also, once sprayed, the jar fails any total-THC test by a mile - but nobody is testing your personal stash.
—
## The box mod question
Crude oil will not work in a sub-ohm tank. Too viscous to wick, and dirty enough to foul the coil in a day.
Three real paths:
- Thin it. 10-20% CBC (a cannabinoid that's naturally thin and cheap) plus <=5% terpenes, in a ceramic-coil pod - Nord with an RPM ceramic 1.2O, or similar. Terpenes alone at high percentages are harsh and eat plastic tanks, which is why CBC matters.
- Dab it. A Sequoia/Divine Tribe-style dab tank or a wax pen handles raw oil fine. Just chazzes.
- Distill it. Only route to something that behaves like a real cart.
—
## My actual recommendation
Two things, and neither is the conversion.
Stockpile now. Buy 100 g of D8 distillate this week, split into amber syringes, freeze. That's maybe $150-250 and it's shelf-stable for years cold, dark, and oxygen-free. That single move covers the next several years of vaping and dosing, and it beats anything you'll produce in a kitchen.
Then learn the conversion as a hedge against distillate becoming hard to order, and point it at edibles and MCT tincture - not carts and not flower. Crude oil is genuinely excellent in a dropper bottle where color and harshness don't matter, and that's the one use case where the messy chemistry is a non-issue. Sprayed flower is a fun project, but it's the worst effort-to-payoff ratio of the three.
Quoted By:
>>4305417
You guys you guys the E-girl asked me to unblock her. It's not over yet. Her hips, btw
